The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Sulfur compounds / Organic S-compounds / CS2...Cl / Dookwah-Roberts(2005)_298K_320-600nm

DATAFILE: CS2...Cl_Dookwah-Roberts(2005)_298K_320-600nm.txt
NAME: carbon disulfide-chlorine adduct
FORMULA: CS2...Cl
AUTHOR(YEAR): Dookwah-Roberts(2005)
T: 298K
λ: 320-600nm
BIBLIOGRAPHY: V. Dookwah-Roberts, R. Soller, J.M. Nicovich, and P.H. Wine, "Spectroscopic and kinetic studies of the gas-phase CS2-Cl adduct", J. Photochem. Photobiol. A: Chem. 176, 114-123 (2005); DOI: 10.1016/j.jphotochem.2005.08.013
COMMENTS: Photolysis at 248 nm of COCl2 in the presence of CS2, and time-resolved UV-VIS absorption spectroscopy

A theoretical interpretation of the experimental spectrum (multireference configuration interaction method and time-dependent density functional theory),

C. Camacho, C.-W. Cheng, H. Witek, and Y.-P. Lee, "Theoretical interpretation of the UV-vis spectrum of the CS2/Cl complex in the spectral region 320-550 nm", J. Phys. Chem. A 114, 11008-11016 (2010),

identified the complex as Cl…SCS, and not Cl…CS2

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